Novel monolayer ferroelectric hybrid structuresScientists at the U.S. Naval Research Laboratory (NRL

Novel monolayer ferroelectric hybrid structuresScientists at the U.S. Naval Research Laboratory (NRL), Materials Science and Technology Division, have demonstrated that the intensity and spectral composition of the photoluminescence emitted from a single monolayer of tungsten disulphide (WS2) can be spatially controlled by the polarization domains in an adjacent film of the ferroelectric material lead zirconium titanate (PZT).These domains are written in the PZT using a conductive atomic force microscope, and the photoluminescence (PL) is measured in air at room temperature. Because the polarization domain wall width in a ferroelectric can be as low as 1-10 nm, this approach enables spatial modulation of PL intensity and the corresponding carrier populations with potential for nanoscale resolution.Single monolayer transition metal dichalcogenides (TMDs) such as WS2 exhibit striking optical properties due to their direct band gap. The dielectric screening is very low due to their two dimensional (2D) character, and thus their properties are strongly affected by their immediate environment, and can be modified and controlled by variations in local charge density due to adsorbates or electrostatic gating. This has generated keen interest in a wide variety of electronic and optical device applications.Read more. -- source link

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